Structure, thermal and magnetic characterization of hydrothermal synthesized Li2CuP2O7 crystals

Gopalakrishna, G. S. and Mahesh, M. J. and Ashamanjari, K. G. and Shashidhara Prasad, J. (2008) Structure, thermal and magnetic characterization of hydrothermal synthesized Li2CuP2O7 crystals. Materials Research Bulletin, 43 (5). 1171 - 1178. ISSN 0025-5408

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Official URL: https://doi.org/10.1016/j.materresbull.2007.05.035

Abstract

New lithium copper(II) pyrophosphate, Li2CuP2O7 crystals were synthesized by the hydrothermal technique at moderate temperature and pressure conditions. The as-synthesized compound was characterized by DTA/TGA, infrared radiation, single crystal XRD and magnetic susceptibility measurement. The compound has crystallized in monoclinic system with C2/c space group and cell parameters a=15.3360(14) Å, b=4.8733(13) Å, β=114.8(1)°, V=585.2(2) Å, having tunnel type of cavities in the structure. Thermal behaviour and structural coordination of the prepared materials were investigated, respectively, using DTA/TGA and FTIR measurements. Magnetic results have revealed; it is a frequency and temperature dependent prospective paramagnetic materials.

Item Type: Article
Uncontrolled Keywords: D. Crystal structure
Subjects: F Earth Science > Geology
Divisions: Department of > Earth Science
Depositing User: Manjula P Library Assistant
Date Deposited: 22 Aug 2019 07:31
Last Modified: 22 Aug 2019 07:31
URI: http://eprints.uni-mysore.ac.in/id/eprint/6885

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