Crystal structure of (2R)-1-(methyl-sulfonyl)oxy]propan-2-aminium chloride: a chiral molecular salt

Rajegowda, H. R. and Palakshamurthy, B. S. and Lokanath, N. K. and Naveen, S. and Kumar, P. R. (2015) Crystal structure of (2R)-1-(methyl-sulfonyl)oxy]propan-2-aminium chloride: a chiral molecular salt. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 71 (10). O733-U298. ISSN 2056-9890

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Official URL: http://doi.org/10.1107/S2056989015016972

Abstract

In the title chiral molecular salt, C4H12NO3S+-Cl-, the cation is protonated at the N atom, producing RNH3](+), where R is CH3SO2OCH2C(H)CH3. The N atom in the cation is spa -hybridized. In the crystal, cations and anions are connected by strong N-H center dot center dot center dot Cl hydrogen bonds to generate edge -shared 12 -membered rings of the form {center dot center dot center dot Cl center dot center dot center dot HNH}(3). This pattern of hydrogen bonding gives rise to zigzag supramolecular layers in the ab plane. The layers are connected into a three-dimensional architecture by CH center dot center dot center dot O hydrogen bonds. The structure was refined as an inversion twin.

Item Type: Article
Uncontrolled Keywords: crystal structure; chiral methanesulfonate; hydrogen bonding; salt
Subjects: D Physical Science > Physics
Divisions: Department of > Physics
Depositing User: Shrirekha N
Date Deposited: 30 May 2019 09:32
Last Modified: 30 May 2019 09:32
URI: http://eprints.uni-mysore.ac.in/id/eprint/684

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