N-(2-{[5-Bromo-2-(morpholin-4-yl)pyrimidin-4-yl]sulfan­yl}-4-meth­­oxy­phen­yl)-4-chloro­benzene­sulfonamide

Kumar, Mohan and Mallesha, L. and Sridhar, M. A. and Kapoor, Kamini and Gupta, Vivek K. and Kant, Rajni (2012) N-(2-{[5-Bromo-2-(morpholin-4-yl)pyrimidin-4-yl]sulfan­yl}-4-meth­­oxy­phen­yl)-4-chloro­benzene­sulfonamide. Acta Crystallographica Section E, 68 (9). o2800. ISSN 2056-9890

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Abstract

In the title compound, C21H20BrClN4O4S2, the benzene rings bridged by the sulfonamide group are tilted relative to each other by a dihedral angle of 70.2 (1)° and the dihedral angle between the sulfur-bridged pyrimidine and benzene rings is 69.5 (1)°. The mol­ecular conformation is stabilized by a weak intra­molecular π–π stacking inter­action between the pyrimidine and the 4-chloro­benzene rings [centroid–centroid distance = 3.978 (2) Å]. The morpholine ring adopts a chair conformation. In the crystal, mol­ecules are linked into inversion dimers by pairs of C—H⋯N hydrogen bonds and these dimers are further connected by N—H⋯O hydrogen bonds, forming a tape along the a axis.

Item Type:	Article
Subjects:	D Physical Science > Physics
Divisions:	Department of > Physics
Depositing User:	C Swapna Library Assistant
Date Deposited:	19 Aug 2019 05:50
Last Modified:	19 Aug 2019 05:50
URI:	http://eprints.uni-mysore.ac.in/id/eprint/6737

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