Magnesium-catalyzed proficient reduction of oximes to amines using ammonium formate

Abiraj, K. and Gowda, D. C. (2004) Magnesium-catalyzed proficient reduction of oximes to amines using ammonium formate. SYNTHETIC COMMUNICATIONS, 34 (4). pp. 599-605. ISSN 0039-7911

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Official URL: https://doi.org/10.1081/SCC-120027707

Abstract

Various aldoximes and ketoximes were selectively reduced to the corresponding amines by catalytic transfer hydrogenation employing low cost magnesium powder and ammonium formate at room temperature. Many other functionalities such as halogens, -OH, -OCH3, -COOH and -CH3 remained unaffected. The hydrogenation is fast, mild, clean, cost effective and high yielding.

Item Type: Article
Uncontrolled Keywords: oximes; amines; ammonium formate; hydrogenation; magnesium powder
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: lpa venkatesh user
Date Deposited: 22 Aug 2019 08:47
Last Modified: 22 Aug 2019 08:47
URI: http://eprints.uni-mysore.ac.in/id/eprint/6621

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