Synthesis and X-ray crystal structure studies of 1-ethyl-3-(2-chlorophenyl)-1,2,3-triazolium perchlorate

Mantelingu, K. and Rangappa, K. S. and Basappa and Doreswamy, B. H. and Mahendra, M. and Sridhar, M. A. and Shashidhara Prasad, J. (2004) Synthesis and X-ray crystal structure studies of 1-ethyl-3-(2-chlorophenyl)-1,2,3-triazolium perchlorate. Journal of Chemical Crystallography volume, 34 (2). pp. 141-145. ISSN 1074-1542

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Abstract

The isolation of stable carbenes of the Arduengo (1a) and Wanzlick (2a) type has prompted us to look for stable nitrenium ions of the related structural type 1-ethyl-3-(2-chloropenyl)-1,2,3-triazolium perchlorate (6(+)ClO(4)(-)). The title compound was synthesized and the structure was investigated by X-ray crystallography. It crystallizes in the monoclinic space group P2(1)/n with cell parameters a = 7.066(4) Angstrom, b = 27.680(6) Angstrom c = 7.486(2) Angstrom, beta = 111.22(3)degrees, and Z = 4. The structure exhibits arrangement of the molecules with intermolecular layers.

Item Type:	Article
Uncontrolled Keywords:	nitrenium ions; carbenes; triazolium perchlorates; crystal structure
Subjects:	C Chemical Science > Chemistry
Divisions:	Department of > Chemistry
Depositing User:	Users 23 not found.
Date Deposited:	21 Aug 2019 06:30
Last Modified:	22 Nov 2022 09:45
URI:	http://eprints.uni-mysore.ac.in/id/eprint/6617

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