Hydrazinium monoformate mediated facile preparation of amines from azides catalyzed by zinc

Prasad, H. S. and Srinivasa, G. R. and Abiraj, K. and Gowda, D. C. (2004) Hydrazinium monoformate mediated facile preparation of amines from azides catalyzed by zinc. INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 43 (8). pp. 1787-1789. ISSN 0019-5103

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Abstract

A variety of functionalized alkyl and aryl primary amines have been prepared from corresponding azides by reaction with hydrazinium monoformate in the presence of low cost commercial zinc dust at room temperature. Many other reducible substituents such as halogen, methoxy, phenol, acid, ethene and nitrile remain unaffected. The hydrogenation is fast, mild, clean, cost-effective and high yielding.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: lpa venkatesh user
Date Deposited: 31 Aug 2019 07:18
Last Modified: 31 Aug 2019 07:18
URI: http://eprints.uni-mysore.ac.in/id/eprint/6558

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