Umesha, K. B. and Rai, K. M. Lokanatha and Mahadeva, N. and Mahadeva, J. (2004) Synthesis and mesomorphic behaviour of 3-4-alkyloxyphenyl]-5-3,4-ethylenedioxybenzyl]-2-isoxazolines. ChemInform, 43 (12). pp. 2635-2640. ISSN 0931-7597
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A simple homologous series of 3-4-alkyloxyphenyl]-5-3,4-methylenedioxybenzyl]-2-isoxazolines having chiral sources have been synthesized by the reaction of nitrile oxides isolated from the dehydrogenation of 4-alkyloxyphenyl aldoximes using chloramine-T with safrole. Synthesized compounds structures have been confirmed by H-1 NMR, C-13 NMR, mass spectral analysis and optical texture studies have been carried out using Leitz polarizing microscope. The synthesized compounds exhibit cholesteric phase or chiral nematic phase (N*), smectic A (S-A) and chiral smectic phases (S-c*), some at and just above room temperature.
| Item Type: | Article |
|---|---|
| Subjects: | C Chemical Science > Chemistry |
| Divisions: | Department of > Chemistry |
| Depositing User: | Users 23 not found. |
| Date Deposited: | 04 Sep 2019 12:06 |
| Last Modified: | 13 Jan 2023 10:50 |
| URI: | http://eprints.uni-mysore.ac.in/id/eprint/6512 |
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