Tamilselvan, P. and Basavaraju, Y. B. and Murugesan, R. and Sampathkumar, E. (2008) Cobalt(II) acetylacetonate catalyzed Friedel–Crafts acylation of anisole, thioanisole, and toluene. Catalysis Communications, 10 (3). 300 - 303. ISSN 1566-7367
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Official URL: https://doi.org/10.1016/j.catcom.2008.09.025
Abstract
A new highly efficient catalytic procedure for the Friedel–Crafts acylation of electron rich aromatics is reported. Cobalt(II) acetylacetonate catalyses the acylation of anisole, thioanisole, and toluene with a variety of acyl chlorides in nitromethane and acetonitrile under mild conditions. The catalyst is found to be reusable and the acylation is regioselective, and affords exclusively C-4 acylated products in excellent yields.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | Cobalt(II) acetylacetonate, Catalysis, Acylation, Anisole, Thioanisole, Nitromethane, Acetonitrile, Solvent effect |
| Subjects: | C Chemical Science > Chemistry |
| Divisions: | Department of > Chemistry |
| Depositing User: | Manjula P Library Assistant |
| Date Deposited: | 16 Aug 2019 06:13 |
| Last Modified: | 16 Aug 2019 06:13 |
| URI: | http://eprints.uni-mysore.ac.in/id/eprint/6407 |
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