The crystal structure of (it E)-2-ethyl-it N-(4-nitro-benzyl-idene)aniline: three-dimensional supra-molecular assembly mediated by CH⋅sO hydrogen bonds and nitro⋅sπ(arene) inter-actions

Girisha, M. and Sagar, B. K. and Yathirajan, H. S. and Rathore, R. S. and Glidewell, Christopher (2018) The crystal structure of (it E)-2-ethyl-it N-(4-nitro-benzyl-idene)aniline: three-dimensional supra-molecular assembly mediated by CH⋅sO hydrogen bonds and nitro⋅sπ(arene) inter-actions. Acta Crystallographica Section E, 74 (8). pp. 1071-1074.

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Abstract

In the molecule of the title compound, Csb 15Hsb 14Nsb 2Osb 2, the 2-ethylphenyl group is disordered over two sets of atomic sites having occupancies of 0.515(19) and 0.485(19), and the dihedral angle between the two partial-occupancy aryl rings is 6(2)circ. A combination of CH⋅sO hydrogen bonds and nitro⋅sπ(arene) inter-actions links the molecules into a continuous three-dimensional framework structure. Comparisons are made with the structures of some related compounds.

Item Type:	Article
Uncontrolled Keywords:	Schiff bases, crystal structure, disorder, molecular conformation, hydrogen bonding, nitro...pi(arene) interactions, supramolecular assembly
Subjects:	C Chemical Science > Chemistry
Divisions:	Department of > Chemistry
Depositing User:	Manjula P Library Assistant
Date Deposited:	08 Aug 2019 10:38
Last Modified:	08 Aug 2019 10:59
URI:	http://eprints.uni-mysore.ac.in/id/eprint/6250

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