An efficient synthesis of tert-butyl ethers/esters of alcohols/amino acids using methyl tert-butyl ether

Mallesha, N. and Rao, S. Prahlada and Suhas, R. and Channe Gowda, D. (2012) An efficient synthesis of tert-butyl ethers/esters of alcohols/amino acids using methyl tert-butyl ether. Tetrahedron Letters, 53 (6). 641 - 645. ISSN 0040-4039

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Official URL: https://doi.org/10.1016/j.tetlet.2011.11.108

Abstract

A facile synthesis of a wide variety of tert-butyl ethers and tert-butyl ester derivatives under mild conditions is described. Alcohols etherified with tert-butyl methyl ether as tert-butyl source and solvent, in the presence of sulfuric acid. Many amino acid tert-butyl esters have been synthesized by this procedure. The reaction is simple, inexpensive, easily scaled up, and proceeds without observable racemization. A green method was developed for the deprotection of this group using Amberlite resin IR 120-H as catalyst.

Item Type: Article
Uncontrolled Keywords: Butyl ether, Butyl esters, MTBE, Molecular sieves
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: C Swapna Library Assistant
Date Deposited: 23 Jul 2019 06:06
Last Modified: 23 Jul 2019 06:06
URI: http://eprints.uni-mysore.ac.in/id/eprint/5460

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