Valyl benzyl ester chloride

Dutkiewicz, Grzegorz and Siddaraju, B. P. and Yathirajan, H. S. and Mayekar, A. N. and Kubicki, Maciej (2010) Valyl benzyl ester chloride. Acta Crystallographica Section E, 66 (2). O324-U2110. ISSN 1600-5368

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In the title compound (systematic name: 1-benz\-yloxy-3-methyl-1-oxobutan-2-aminium chloride), C\sb 12H\sb 18NO\sb 2\sp +⋅Cl\sp -}}, the ester group is approximately planar, with a maximum deviation of 0.040(2)Å from the least-squares plane, and makes a dihedral angle of 28.92(16)\circ with the phenyl ring. The crystal structure is organized by N—-H⋅sCl hydrogen bonds which join the two components into a chain along the \it b axis. Pairs of chains arranged anti\-parallel are inter\-connected by further N—-H⋅sCl hydrogen bonds, forming eight-membered rings. Similar packing modes have been observed in a number of amino acid ester halides with a short unit-cell parameter of \it ca 5.5Å along the direction in which the chains run.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: LA manjunath user
Date Deposited: 16 Jul 2019 05:08
Last Modified: 16 Jul 2019 05:08

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