Orphenadrinium picrate picric acid

Fun, Hoong-Kun and Hemamalini, Madhukar and Siddaraju, B. P. and Yathirajan, H. S. and Narayana, B. (2010) Orphenadrinium picrate picric acid. Acta Crystallographica Section E, 66 (3). O682-O683. ISSN 1600-5368

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Official URL: https://doi.org/10.1107/S1600536810006379


The asymmetric unit of the title compound \it N,\it N-dimethyl-2-(2-methyl{\-}phen{\-}yl)phenyl{\-}meth{\-}oxyethanaminium picrate picric acid, C${\sb 18}$H${\sb 24}$NO${\sp +}${$\cdot$}C${\sb 6}$H${\sb 2}$N${\sb 3}$O${\sb 7}$${\sp {$-$}}${$\cdot$}C${\sb 6}$H${\sb 3}$N${\sb 3}$O${\sb 7}$, contains one orphenadrinium cation, one picrate anion and one picric acid mol{\-}ecule. In the orphenadrine cation, the two aromatic rings form a dihedral angle of 70.30(7){$^\circ$}. There is an intra{\-}molecular O{---}H{$\cdots$}O hydrogen bond in the picric acid mol{\-}ecule, which generates an {\it S}(6) ring motif. In the crystal structure, the orphenadrine cations, picrate anions and picric acid mol{\-}ecules are connected by strong inter{\-}molecular N{---}H{$\cdots$}O hydrogen bonds, {$\pi$}{$\cdots$}{$\pi$} inter{\-}actions between the benzene rings of cations and anions centroid{--}centroid distance = 3.5603(9){\AA} and weak C{---}H{$\cdots$}O hydrogen bonds, forming a three-dimensional network.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: LA manjunath user
Date Deposited: 15 Jul 2019 10:49
Last Modified: 15 Jul 2019 10:49
URI: http://eprints.uni-mysore.ac.in/id/eprint/5216

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