(2\it E)-1-(4-Bromo\-phen\-yl)-3-(4-fluoro\-phen\-yl)prop-2-en-1-one

Dutkiewicz, Grzegorz and Veena, K. and Narayana, B. and Yathirajan, H. S. and Kubicki, Maciej (2010) (2\it E)-1-(4-Bromo\-phen\-yl)-3-(4-fluoro\-phen\-yl)prop-2-en-1-one. Acta Crystallographica Section E, 66 (5). O1243-O1244. ISSN 1600-5368

Text (Full Text) (2E)-1-(4-Bromophenyl)-3-(4-fluorophenyl)prop-2-en-1-one.pdf - Published Version Download (724kB)

Abstract

The title compound, C\sb 15H\sb 10BrFO, is isostructural with (2\it E)-1-(4-chloro\-phen\-yl)-3-(4-fluoro\-phen\-yl)prop-2-en-1-one Qiu {\it et al.} (2006). {\it Acta Cryst.} E{\bf 62}, o3525{--}o3526, but the structures of other dihalogen analogues, without fluorine, are different, although they are also isostructural within the series. The mol{\-}ecule is approximately flat, the dihedral angle between the ring planes being 8.49(13){$^\circ$}. In the crystal structure, inter{\-}molecular C{---}H{$\cdots$}O, C{---}H{$\cdots$}F and C{---}H{$\cdots$}Br hydrogen bonds link mol{\-}ecules into V-shaped ribbons running parallel to 101 and stacked with an inter{\-}planar distance of approximately 3.53{\AA} (centroid{--}vcentroid distance = 3.857{\AA})..

Item Type:	Article
Subjects:	C Chemical Science > Chemistry
Divisions:	Department of > Chemistry
Depositing User:	LA manjunath user
Date Deposited:	12 Jul 2019 06:17
Last Modified:	12 Jul 2019 06:17
URI:	http://eprints.uni-mysore.ac.in/id/eprint/5133

Actions (login required)

View Item