2-(4-Methoxy\-phen\-yl)-6-trifluoro\-methyl-1\it H-pyrrolo3,2-{\it c}quinoline monohydrate

Dutkiewicz, Grzegorz and Mayekar, Anil N. and Yathirajan, H. S. and Narayana, B. and Kubicki, Maciej (2010) 2-(4-Methoxy\-phen\-yl)-6-trifluoro\-methyl-1\it H-pyrrolo3,2-{\it c}quinoline monohydrate. Acta Crystallographica Section E, 66 (5). O1111-O1112. ISSN 1600-5368

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Official URL: https://doi.org/10.1107/S1600536810013644


In the title compound, C\sb 19H\sb 13F\sb 3N\sb 2O⋅H\sb 2O, the phenyl and pyrroloquinoline ring system are close to coplanar dihedral angle = 10.94(4){$^\circ$}. The meth{\-}oxy group also is almost coplanar with the phenyl ring 5.4(1){$^\circ$}. In the crystal structure N{---}H{$\cdots$}O(water) and water{--}quinoline O{---}H{$\cdots$}N hydrogen bonds build up a supra{\-}molecular chain-like arrangement along 001. The remaining H atom of the water mol{\-}ecule does not take part in classical hydrogen bonds. Instead, this O{---}H bond points toward the center of the phenyl ring of a neighbouring mol{\-}ecule. Weak C{---}H{$\cdots$}O and C{---}H{$\cdots$}{$\pi$} inter{\-}actions are also present.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: LA manjunath user
Date Deposited: 12 Jul 2019 06:11
Last Modified: 12 Jul 2019 06:11
URI: http://eprints.uni-mysore.ac.in/id/eprint/5130

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