Electronically semitransparent ZnO nanorods with superior electron transport ability for DSSCs and solar photocatalysis

Hezam, Abdo and Namratha, K. and Drmosh, Q. A. and Chandrashekar, B. N. and Jayaprakash, G. K. and Cheng, Chun and Srikantaswamy, S. and Byrappa, K. (2018) Electronically semitransparent ZnO nanorods with superior electron transport ability for DSSCs and solar photocatalysis. Ceramics International, 44 (6). 7202 - 7208. ISSN 1873-3956

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Official URL: https://doi.org/10.1016/j.ceramint.2018.01.167

Abstract

Oxygen vacancies (VO) as intrinsic defects play a key role in determining zinc oxide (ZnO) properties. Herein, ZnO nanorods with uniform morphology have been synthesized via hydrothermal method. The obtained nanorods appear semitransparent in SEM images indicating their electron semitransparent nature (ESN). Dye sensitized solar cells (DSSCs) studies reveal the superior electron transport property of the prepared nanorods further confirming their ESN. XPS, optical absorption, and DSSCs results suggest that the origin of ESN is the presence of an appropriate amount of VO in the ZnO nanorods. Moreover, the obtained ZnO nanorods exhibit excellent photocatalytic activity in decomposition of phenol under sunlight irradiation which is attributed to VO. Our study introduces a fundamental insight into the role of VO in inducing ESN as a new property for ZnO.

Item Type: Article
Uncontrolled Keywords: Electronically semitransparent, ZnO nanorods, Dye sensitized solar cells, Oxygen vacancies, Solar photocatalysis
Subjects: D Physical Science > Material Science
Divisions: Department of > Material Science
Depositing User: Manjula P Library Assistant
Date Deposited: 10 Jul 2019 07:11
Last Modified: 21 Dec 2020 05:12
URI: http://eprints.uni-mysore.ac.in/id/eprint/5054

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