One-pot synthesis of 2,3-substituted benzobthiophenes via cu(i) catalysed intramolecular cyclisation from dithioesters

Sandhya, N. C. and Nandeesh, K. N. and Rangappa, K. S. and Ananda, S. (2015) One-pot synthesis of 2,3-substituted benzobthiophenes via cu(i) catalysed intramolecular cyclisation from dithioesters. RSC Advances, 5 (38). pp. 29939-29946.

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Official URL: http://doi.org/10.1039/C5RA02114F

Abstract

Efficient synthesis of benzo[b]thiophenes from o-halophenyl acetonitrile has been achieved. This novel one-pot procedure involves CuI and pivalic acid catalyzed C–S bond formation using dithioesters followed by a heterocyclization reaction. This efficient protocol has the advantages of one-pot synthesis, short reaction time, good yields (62–78%) and operational simplicity.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: Users 19 not found.
Date Deposited: 08 Jul 2019 09:55
Last Modified: 23 Oct 2019 10:43
URI: http://eprints.uni-mysore.ac.in/id/eprint/4891

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