(\it E)-1-(2,5-Dichloro-3-thien\-yl)-3-(3,4-dimeth\-oxy\-phen\-yl)prop-2-en-1-one

Harrison, William T. A. and Chidan Kumar, C. S. and Yathirajan, H. S. and Mayekar, A. N. and Narayana, B. (2010) (\it E)-1-(2,5-Dichloro-3-thien\-yl)-3-(3,4-dimeth\-oxy\-phen\-yl)prop-2-en-1-one. Acta Crystallographica Section E, 66 (10). O2479-U1648. ISSN 1600-5368

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Official URL: https://doi.org/10.1107/S1600536810035142


In the title compound, C\sb 15H\sb 12Cl\sb 2O\sb 3S, the prop-2-en-1-one (enone) fragment is almost planar C{---}C{---}C{---}O = 2.2(4){$^\circ$} and it subtends dihedral angles of 11.9(2) and 11.0(2){$^\circ$} with the thio{\-}phene and benzene rings, respectively. The dihedral angle between the aromatic rings is 3.47(16){$^\circ$}. In the crystal, weak C{---}H{$\cdots$}O and C{---}H{$\cdots$}Cl inter{\-}actions link the mol{\-}ecules, leading to {\it R}${\sb 2}$${\sp 2}$(14), {\it R}${\sb 2}$${\sp 2}$(24) and {\it C}(11) supra{\-}molecular motifs occurring within the three-dimensional network. Weak aromatic {$\pi$}{--}{$\pi$} stacking centroid{--}centroid separations = 3.6823(15) and 3.8722(15){\AA} may also help to consolidate the packing.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: LA manjunath user
Date Deposited: 08 Jul 2019 09:44
Last Modified: 08 Jul 2019 09:44
URI: http://eprints.uni-mysore.ac.in/id/eprint/4886

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