Oxidation of para-methoxy benzaldehyde and salicylaldehyde by N-sodio-N-chlorotoluene sulphonamide (chloramine-T) in acid medium: A kinetic and mechanistic study

Venkatachalapathy, R. and Veerabhadraswamy, M. and Rangaswamy, (2001) Oxidation of para-methoxy benzaldehyde and salicylaldehyde by N-sodio-N-chlorotoluene sulphonamide (chloramine-T) in acid medium: A kinetic and mechanistic study. ASIAN JOURNAL OF CHEMISTRY, 13 (1). pp. 221-225.

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Abstract

The kinetics of oxidation of para-methoxy benzaldehyde and salicylaldehyde by chloramine-T (CAT) have been investigated in hydrochloric acid medium at 303 K. The rate shows first order dependence on CAT] and fractional order in aldehyde]. The rate increases with increase in HCl] and shows first order dependence on H+] and Cl-], variation of ionic strength, addition of reaction product (para-toluene sulphonamide) and change in dielectric constant of the medium had no significant effect on the reaction rate. Thermodynamic parameters are evaluated.

Item Type: Article
Subjects: Physical Sciences > Chemistry
Divisions: PG Campuses > Manasagangotri, Mysore > Chemistry
Depositing User: Users 12 not found.
Date Deposited: 24 Apr 2013 11:05
Last Modified: 02 Dec 2015 07:38
URI: http://eprints.uni-mysore.ac.in/id/eprint/4805

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