Oxidation of methionine by sodium N-chlorobenzene sulphonamide in hydrochloric acid medium: A kinetic study

Ananda, M. S. and Rangaswamy, (2001) Oxidation of methionine by sodium N-chlorobenzene sulphonamide in hydrochloric acid medium: A kinetic study. ASIAN JOURNAL OF CHEMISTRY, 13 (2). pp. 543-549.

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Abstract

Kinetics of oxidation of DL-methionine (Met) in the presence of HCl by sodium N-chlorobenzene sulphonamide (chloramine-B or CAB) have been performed at 30 degreesC. The rate shows a first order dependence each on CAB] and H+] and zero order dependence on Met]. The variation of the ionic strength, dielectric constant of the medium and addition of chloride ion and the reaction product of CAB (benzene sulphonamide) do not have any significant effect on the reaction rate. The activation parameters have been evaluated.

Item Type: Article
Subjects: Physical Sciences > Chemistry
Divisions: PG Campuses > Manasagangotri, Mysore > Chemistry
Depositing User: Users 12 not found.
Date Deposited: 23 Apr 2013 10:51
Last Modified: 04 Jul 2013 08:17
URI: http://eprints.uni-mysore.ac.in/id/eprint/4786

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