4-({E})-(4-{Chlorobenzylidene})amino-3-methyl-1H-1,2,4-triazole-5(4H)-thione

Sarojini, B. K. and Manjula, P. S. and Kaur, M. and Anderson, B. J. and Jasinski, J. P. (2014) 4-({E})-(4-{Chlorobenzylidene})amino-3-methyl-1H-1,2,4-triazole-5(4H)-thione. Acta Crystallographica Section E: Structure Reports Online, 70 (1). o57-o58. ISSN 1600-5368

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Abstract

In the title compound, C10H9ClN4S, the dihedral angle between the mean planes of the phenyl and 1H-1,2,4-triazole-5(4H)-thione rings is 25.3 (9)°. The latter ring is essentially planar, with maximum deviations of 0.010 and -0.010 Å for the ring N atom in the 4-position and ring C atom bearing the methyl group, respectively. An intra­molecular C-H...S contact occurs. In the crystal, pairs of weak N-H...S inter­actions link the mol­ecules into inversion dimers in the ac plane, forming R22(8) graph-set motifs. In addition, weak [pi]-[pi] inter­actions [centroid-centroid distances = 3.3463 (14) and 3.6127 (13)Å] are observed.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Depositing User: Arshiya Kousar
Date Deposited: 03 Jul 2019 10:45
Last Modified: 03 Jul 2019 10:45
URI: http://eprints.uni-mysore.ac.in/id/eprint/4504

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