Synthesis, characterization, crystal structure, and thermal analysis of 4-(3-acetylphenyl)amino-2-methylidene-4-oxobutanoic acid

Nayak, P. S. and Narayana, B. and Anthal, Sumati and Gupta, V. K. and Kant, R. and Yathirajan, H. S. (2014) Synthesis, characterization, crystal structure, and thermal analysis of 4-(3-acetylphenyl)amino-2-methylidene-4-oxobutanoic acid. Molecular Crystals and Liquid Crystals, 592 (1). pp. 249-258. ISSN 1542-1406

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Official URL: https://doi.org/10.1080/15421406.2013.858582

Abstract

4-(3-Acetylphenyl)amino-2-methylidene-4-oxobutanoic acid (1) is synthesized by a ring opening reaction of itaconic anhydride with 3-aminoacetophenone and characterized by FT-IR, 1H NMR, UV-Vis, TGA, DTA, and single crystal X-ray diffraction. The crystal of 1 belongs to triclinic unit cell in the P-1 space group with the unit cell dimensions a = 4.9485(3), b = 5.3614(6), c = 22.457(2) à , α = 88.295(8), β = 89.379(7), γ = 84.495(7), and Z = 2 The crystal structure is solved by direct methods using single-crystal X-ray diffraction data collected at room temperature and refined by full-matrix least-squares procedures to a final R-value of 0.0467 for 1623 observed reflections. Intermolecular N\&sbnd;H.O and O\&sbnd;H.O hydrogen bonds links the molecules into chains along 010 direction. In addition the thermal stability of the 1 is determined by using DTA, TGA analysis, and wavelength absorption at λmax = 297 nm is determined by UV-Vis spectrophotometer. Copyright © Taylor \& Francis Group, LLC.

Item Type: Article
Uncontrolled Keywords: Crystal structure, Hydrogen bonds, Single crystals, Single crystal x-ray diffraction, Synthesis (chemical), Unit-cell dimensions, X ray diffraction, Intermolecular interactions, Nuclear magnetic resonance spectroscopy, Thermoanalysis, FTIR, Thermodynamic properties, 3-Aminoacetophenone, Itaconic anhydrides, Least squares approximations, NMR spectrum, UV-Vis spectrophotometers
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: Arshiya Kousar
Date Deposited: 02 Jul 2019 11:28
Last Modified: 16 Nov 2019 10:04
URI: http://eprints.uni-mysore.ac.in/id/eprint/3949

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