Synthesis and characterization of stable nitrenium ion complex: 1-Hydroxy-3-methyl benzotriazolium trifluromethane sulfonate

Doreswamy, B. H. and Chandra and Mantelingu, K. and Sridhar, M. A. and Mahendra, M. (2014) Synthesis and characterization of stable nitrenium ion complex: 1-Hydroxy-3-methyl benzotriazolium trifluromethane sulfonate. Research on Chemical Intermediates, 40 (8). pp. 2659-2665. ISSN 0922-6168

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Abstract

The isolation of stable carbenes of the Arduengo and Wanzlick type has prompted us to look for stable nitrenium ions of the related structural type 1-Hydroxy-3-methyl benzotriazolium trifluromethane sulfonate. Nitrenium ions are azocations with structure and survive long enough under in vitro conditions to bind with biological nucleophiles, i.e. DNA bases, and play an important role in carcinogenic processes involving the metabolism of aromatic amines. The title compound (C15H16F3N6O5S) was isolated and crystallized in the monoclinic space group Cc with cell parameters a = 19.866(1) Å, b = 13.128(9) Å, c = 7.673(5) Å, and Z = 4. The structure has both intra- and intermolecular hydrogen bonds.

Item Type:	Article
Uncontrolled Keywords:	Crystal structure, Hydrogen bonds, Amines, Ions, Monoclinic space groups, Synthesis and characterizations, Carbenes, Carcinogenic process, Intra- and intermolecular hydrogen bonds, Nitrenium ions, Structural type, Trifluromethane
Subjects:	C Chemical Science > Chemistry D Physical Science > Physics
Divisions:	Department of > Chemistry Department of > Physics
Depositing User:	Arshiya Kousar Library Assistant
Date Deposited:	19 Jun 2019 11:11
Last Modified:	19 Jun 2019 11:11
URI:	http://eprints.uni-mysore.ac.in/id/eprint/3328

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