Highly diastereoselective synthesis of polycyclic amines via redox neutral C-H functionalization

Pavan Kumar, C. S. and Harsha, K. B. and Sandhya, N. C. and Ramesha, A. B. and Mantelingu, K. and Rangappa, K. S. (2015) Highly diastereoselective synthesis of polycyclic amines via redox neutral C-H functionalization. NEW JOURNAL OF CHEMISTRY, 39 (11). pp. 8397-8404. ISSN 1369-9261

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Official URL: http://doi.org/10.1039/c5nj01706h

Abstract

Synthesis of polycyclic amines was achieved by benzoic acid catalysed reaction of 1-aryl THIQs and 1-aryl trypolines with o-allyl salicylaldehydes through the in situ generated azomethine ylide intermediates that undergo intramolecular 3+2]-cycloadditions with four new stereogenic centers in excellent diastereoselectivities under simple and mild conditions.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: Shrirekha N
Date Deposited: 18 Jun 2019 05:16
Last Modified: 24 Dec 2019 09:24
URI: http://eprints.uni-mysore.ac.in/id/eprint/3246

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