Srinivasa, H. T. and Palakshamurthy, B. S. and Velmurugan, D. and Devarajegowda, H. C. and Hariprasad, S. (2015) Liquid/single crystal structure analysis: synthesis and characterization of a trimethylsilyl derived rod shaped mesogen. ACTA CHIMICA SLOVENICA, 62 (4). pp. 768-774. ISSN 1580-3155
Full text not available from this repository. (Request a copy)Abstract
4-4'-Cyanophenoxy-carbonyl-phenyl-4-(trimethylsilyl) ethynyl]benzoate a rod shaped liquid crystal (SmA) is synthesized and characterized. The single-crystals were grown in triclinic crystal system in the space group of Pi with unit cell parameters a = 5.9577(2) angstrom, b = 8.0398(3) angstrom, c = 25.8842(9) angstrom, alpha = 86.096(2)degrees, beta = 89.912(2)degrees, gamma = 2.919(2)degrees, Z = 2 , and V = 1182.16(7). The crystal structure is stabilized by C-H center dot center dot center dot O intra-molecular interactions. Further ,the structure also involves C-H center dot center dot center dot pi interactions and weak pi-pi stacking interactions centroid-centroid separation = 3.806 (3) angstrom].
| Item Type: | Article |
|---|---|
| Subjects: | D Physical Science > Physics |
| Divisions: | Yuvaraj college > Physics |
| Depositing User: | Users 19 not found. |
| Date Deposited: | 17 Jun 2019 10:04 |
| Last Modified: | 11 Dec 2019 05:34 |
| URI: | http://eprints.uni-mysore.ac.in/id/eprint/3234 |
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