Ethyl 1-(4-fluoro­benz­yl)-2-(4-meth­­oxy­phen­yl)-1H-benzo[d]imidazole-5-carboxyl­ate

Naveen, S. and Vasantha Kumar and Poojary, Boja and Vishwanatha, P. and Lokanath, N. K. and Abdoh, M. M. M. (2016) Ethyl 1-(4-fluoro­benz­yl)-2-(4-meth­­oxy­phen­yl)-1H-benzo[d]imidazole-5-carboxyl­ate. IUCrData, 1 (11). x161744. ISSN 2414-3146

[img] Text (Full Text)
Ethyl 1-(4-fluorobenzyl)-2-(4-methoxyphenyl)-1H-benzo[d]imidazole-5-carboxylate.pdf - Published Version

Download (449kB)
Official URL:


The title benzoimidazole derivative, C\sb 24H\sb 21FN\sb 2O\sb 3, is T-shaped, with the meth\-oxy\-phenyl and fluoro\-benzyl rings inclined to the benzoimidazole ring system by 40.91(8) and 86.04(8)\circ, respectively, indicating that the fluoro\-benzyl ring system is nearly orthogonal to the benzoimidazole ring system. The fluoro\-benzyl and meth\-oxy\-phenyl rings are inclined to one another by 78.90(10)\circ. In the crystal, mol\-ecules are linked \it via two pairs of C—-H⋅sO hydrogen bonds, forming inversion dimers with \it R\sb 2\sp 2(28) and \it R\sb 2\sp 2(22) ring motifs. As a result of these hydrogen bonds, ribbons propagating along 010 are formed.

Item Type: Article
Uncontrolled Keywords: crystal structure, benzoimidazole, methoxyphenyl, fluorobenzyl, C-H...O hydrogen bonds
Subjects: C Chemical Science > Chemistry
D Physical Science > Physics
Divisions: Department of > Institution of Excellence
Depositing User: manjula User
Date Deposited: 15 Jun 2019 09:46
Last Modified: 15 Jun 2019 09:46

Actions (login required)

View Item View Item