Transition metal free chemoselective reduction of alpha,beta-unsaturated ketones to saturated ketones using tosyl hydrazide as a hydrogen donor

Girish, Y. R. and Raghavendra, K. R. and Nagaraja, D. and Kumar, K. S. S. and Shashikanth, S. (2015) Transition metal free chemoselective reduction of alpha,beta-unsaturated ketones to saturated ketones using tosyl hydrazide as a hydrogen donor. CHINESE JOURNAL OF CHEMISTRY, 33 (2). pp. 181-184. ISSN 1614-7065

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Official URL: https://doi.org/10.1002/cjoc.201400684

Abstract

An efficient, inexpensive and simple method for the reduction of various ,-unsaturated ketones to corresponding saturated ketones using tosyl hydrazide as a hydrogen donor in DMF using calcium oxide powder has been reported. A variety of enones underwent reduction without forming undesirable side products. High chemoselectivity, broad functional group tolerance and good yields are the noteworthy features of this protocol.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: Shrirekha N
Date Deposited: 17 Jun 2019 04:41
Last Modified: 17 Jun 2019 04:41
URI: http://eprints.uni-mysore.ac.in/id/eprint/2792

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