Hydrothermal synthesis and photocatalytic properties of modified and unmodified zinc oxide nanoparticles

Namratha, K. and Nayan, M. B. and Byrappa, K. (2011) Hydrothermal synthesis and photocatalytic properties of modified and unmodified zinc oxide nanoparticles. MATERIALS RESEARCH INNOVATIONS, 15 (1). pp. 36-42.

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Official URL: https://doi.org/10.1179/143307511X12922272563743

Abstract

Zinc oxide (ZnO) nanoparticles have been modified using caprylic acid and n-butylamine as surface modifiers through in situ surface modification under mild hydrothermal conditions (T=150-250 degrees C; P=autogenous). The surface modification was carried out using different molar concentrations of ZnO (1-4M) in the starting materials with an acidic mineraliser like 1 N HCl. The resultant products obtained were either hydrophobic or hydrophilic depending upon the surface modifier used. The ZnO nanoparticles synthesised were subjected to a systematic characterisation using powder X-ray diffraction, Fourier transform infrared spectroscopy, SEM, ultravioletvisible spectroscopy and photocatalytic degradation studies. The hydrophilic ZnO was used in the photocatalytic degradation of indigo carmine dye, and it shows 98% efficiency with a residence time of 4 h.

Item Type: Article
Uncontrolled Keywords: Hydrothermal synthesis; In situ surface modification; Surface modified ZnO nanoparticles; Photocatalytic degradation
Subjects: F Earth Science > Geology
Divisions: Department of > Geography
Depositing User: Users 23 not found.
Date Deposited: 20 Jun 2019 10:12
Last Modified: 20 Jun 2019 10:12
URI: http://eprints.uni-mysore.ac.in/id/eprint/2579

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