(1RS, 6SR)-Ethyl 4-(2,4-dichlorophenyl)-6-(4-fluorophenyl)-2-oxocyclohex-3-ene-1-carboxyl ate

Dutkiewicz, G. and Narayana, B. and Veena, K. and Yathirajan, H. S. and Kubicki, M. (2011) (1RS, 6SR)-Ethyl 4-(2,4-dichlorophenyl)-6-(4-fluorophenyl)-2-oxocyclohex-3-ene-1-carboxyl ate. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 67 (2). O445-U1334. ISSN 1600-5368

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Official URL: doi:10.1107/S160053681100184X


There are two symmetry-independent molecules in the asymmetric unit of the title compound, C21H17Cl2FO3. Both these molecules are very similar: the normal probability plots for bond lengths, angles and even for torsion angles show that the differences are of a statistical nature. A pseudocentre of symmetry is located between the symmetry-independent molecules at 0.245 (1), 0.535 (19), 0.909 (1)]. The cyclohexene rings have slightly distorted sofa conformations in both molecules and the two benzene rings are inclined by dihedral angles of 61.33 (14) and 62.85 (14)degrees. In the crystal, relatively short intermolecular C-H center dot center dot center dot O interactions join molecules into homomolecular (i.e. center dot center dot center dot AAA center dot center dot center dot and center dot center dot center dot BBB center dot center dot center dot) chains along the b axis. These chains are interconnected by further heteromolecular C-H center dot center dot center dot O interactions.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: Users 23 not found.
Date Deposited: 24 Jun 2019 10:05
Last Modified: 24 Jun 2019 10:05
URI: http://eprints.uni-mysore.ac.in/id/eprint/2562

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