1-(2-Hydroxyethyl)-4-{3-(E)-2-(trifluoromethyl)-9H-thioxanthen-9-yli dene]propyl}piperazine-1,4-diium bis(3-carboxyprop-2-enoate)

Siddegowda, M. S. and Butcher, R. J. and Akkurt, M. and Yathirajan, H. S. and Ramesh, A. R. (2011) 1-(2-Hydroxyethyl)-4-{3-(E)-2-(trifluoromethyl)-9H-thioxanthen-9-yli dene]propyl}piperazine-1,4-diium bis(3-carboxyprop-2-enoate). ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 67 (8). O2017-U349.

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Abstract

In the title salt, C23H27F3N2OS+center dot 2C(4)H(3)O(4)(-), a non-merohedral twin ratio of the twin components = 0.402 (1):0.598 (1)], the -CF3 group is disordered over two sets of sites with occupancy factors in the ratio 0.873 (2):0.127 (2). The dihedral angle between the two outer aromatic rings of the 9H-thioxanthene unit, whose thiopyran ring has a screw-boat conformation, is 33.01 (9)degrees. The diprotonated piperazine ring adopts a chair conformation. In the crystal, intermolecular O-H center dot center dot center dot O, N-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds between neighboring molecules form zigzag chains along the a axis and contribute to the stabilization of the packing.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: lpa venkatesh user
Date Deposited: 25 Jul 2019 11:34
Last Modified: 25 Jul 2019 11:34
URI: http://eprints.uni-mysore.ac.in/id/eprint/2432

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