1,3-Bis(4-fluorophenyl)-N,N `-(propane-1,3-diylidene)dihydroxylamine

Samshuddin, S. and Butcher, R. J. and Akkurt, M. and Narayana, B. and Yathirajan, H. S. and Sarojini, B. K. (2011) 1,3-Bis(4-fluorophenyl)-N,N `-(propane-1,3-diylidene)dihydroxylamine. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 67 (8). O1954-U2259. ISSN 1600-5368

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Official URL: doi:10.1107/S1600536811026547

Abstract

The title compound, C15H12F2N2O2, crystallizes with two molecules (A and B) in the asymmetric unit. Both aromatic rings of both molecules are disordered over two orientations occupancy ratios of 0.768 (3):0.232 (3) and 0.770 (3):0.230 (3) for molecule A and 0.789 (3):0.211 (3) and 0.789 (3):0.211 (3) for molecule B]. The dihedral angles between the planes of the major and minor components of the disordered aromatic rings are 72.0 (4) and 71.2 (4)degrees for molecule A, and 70.2 (4) and 71.5 (2)degrees for molecule B. In the crystal, both molecules form inversion dimers with R-2(2)(6) ring motifs via pairs of intermolecular O-H center dot center dot center dot N hydrogen bonds. The dimers are linked, forming zigzag C(7) chains along the c axis. Weak C-H center dot center dot center dot pi interactions help to consolidate the packing.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: lpa venkatesh user
Date Deposited: 25 Jul 2019 11:24
Last Modified: 25 Jul 2019 11:24
URI: http://eprints.uni-mysore.ac.in/id/eprint/2430

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