Tramadolium 2-chlorobenzoate

Sheshadri, S. N. and Nagendra, P. and Siddaraju, B. P. and Byrappa, K. and Lokanath, N. K. and Madan Kumar, S. (2016) Tramadolium 2-chlorobenzoate. IUCrData, 1 (1). ISSN 2414-3146

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Official URL: https://doi.org/10.1107/S2414314616000146

Abstract

In the title molecular salt, C16H26NO2+.C7H4ClO2-,{systematic name: [2-hydroxy-2-(3-methoxyphenyl)cyclohexylmethyl]dimethylammonium 2-chlorobenzoate}, the cyclohexane ring of the cation exhibits a chair conformation with the aromatic and amine substituents in equatorial orientations and the hydroxyl group in an axial orientation. In the anion, the dihedral angle between the aromatic ring and the carboxylate group is 39.16 (13)degrees. In the crystal, the cations are linked to the anions by O-H...O, N-H...O and C-H...O hydrogen bonds, generating [010] chains. Further C-H...O and C-H...[pi] interactions are also observed, which link the chains into a three-dimensional framework.

Item Type: Article
Additional Information: Unmapped bibliographic data: JA - IUCrData [Field not mapped to EPrints] JO - IUCrData [Field not mapped to EPrints]
Uncontrolled Keywords: Tramadol, cyclohexane, crystal structure
Subjects: Physical Sciences > Physics
Divisions: PG Campuses > Manasagangotri, Mysore > Physics
Depositing User: Praveen Kumari B.L
Date Deposited: 22 Aug 2017 10:00
Last Modified: 22 Aug 2017 10:00
URI: http://eprints.uni-mysore.ac.in/id/eprint/19840

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