Highly diastereoselective synthesis of polycyclic amines via redox neutral C-H functionalization

Pavan Kumar, Chottanahalli S. and Harsha, Kachigere B. and Sandhya Nagarakere, C. and Ajjalli Ramesha, B. and Mantelingu, Kempegowda and Rangappa, K. S. (2015) Highly diastereoselective synthesis of polycyclic amines via redox neutral C-H functionalization. New Journal of Chemistry, 39 (11). pp. 8397-8404.

[img]
Preview
Text (Full Text)
Highly diastereoselective synthesis of polycyclic.pdf - Published Version

Download (1626Kb) | Preview
Official URL: http://dx.doi.org/10.1039/C5NJ01706H

Abstract

Synthesis of polycyclic amines was achieved by benzoic acid catalysed reaction of 1-aryl THIQs and 1-aryl trypolines with o-allyl salicylaldehydes through the in situ generated azomethine ylide intermediates that undergo intramolecular 3+2-cycloadditions with four new stereogenic centers in excellent diastereoselectivities under simple and mild conditions.

Item Type: Article
Subjects: Physical Sciences > Chemistry
Divisions: PG Campuses > Manasagangotri, Mysore > Chemistry
Depositing User: Ms. Manjula p
Date Deposited: 24 Mar 2016 11:14
Last Modified: 24 Mar 2016 11:14
URI: http://eprints.uni-mysore.ac.in/id/eprint/18341

Actions (login required)

View Item View Item