Structural, Optical, Spectral, Thermal and Third-Order Nlo Behaviour of 4-Chlorobenzhydrazide Trichloro Acetate Single Crystal

Arunagiri, C. and Selvakumar, S and Lokanath, N. K. (2022) Structural, Optical, Spectral, Thermal and Third-Order Nlo Behaviour of 4-Chlorobenzhydrazide Trichloro Acetate Single Crystal. Brazilian Journal of Physics, 52 (3). ISSN 1678-4448

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Abstract

Hirshfeld surface analysis and molecular structure determination of 4-chlorobenzhydrazide trichloro acetate (4CBTCA) single crystals has been grown by the slow evaporation method at room temperature. The title compound was confirmed by single and powder X-ray diffraction studies. The determination of the single crystal structure establishes that the title compound associate with the triclinic system with the space group P 1¯¯¯. Powder XRD affirmed the crystalline nature of the crystal. The molecular structure and existence of the vibrations were revealed by NMR experiments. The identity of distinct functional groups of title of the compound was determined by FT-IR and FT-Raman spectral analyses. UV–Vis–NIR analysis was performed to examine the optical property of the grown crystal, and the maximum absorbance wavelength is realized at 390 nm. This study discusses the 4-chlorobenzhydrazide trichloro acetate crystal and demonstrates blue and green emissions at 440 and 544 nm. The thermal behaviour of the (4CBTCA) was studied by thermo-gravimetric analysis (TGA), differential thermal analysis (DTA) and differential scanning calorimetry (DSC). Third-order nonlinear refractive index and nonlinear absorption coefficient have been determined by the third-order NLO studies.

Item Type:	Article
Subjects:	D Physical Science > Physics
Divisions:	Department of > Physics
Depositing User:	C Swapna Library Assistant
Date Deposited:	15 Jun 2023 05:43
Last Modified:	15 Jun 2023 05:43
URI:	http://eprints.uni-mysore.ac.in/id/eprint/17530

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