Structure of 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9-hexadecafluorodecyl 1,10-ditosylate by X-ray crystallography and F-19-NMR spectroscopy

Devaraja, S. and Lokanath, N. K. and Sridhar, M. A. and Shashidhara Prasad, J. and Venkatesan, K. and Bhattacharya, Santanu (1999) Structure of 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9-hexadecafluorodecyl 1,10-ditosylate by X-ray crystallography and F-19-NMR spectroscopy. Journal of Molecular Structure, 479 (1). pp. 75-81. ISSN 0022-2860

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Official URL: https://doi.org/10.1016/S0022-2860(98)00797-2

Abstract

2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9-hexadecafluorodecyl 1,10-ditosylate and its precursors were synthesized and characterized by H-1- and F-19-NMR spectroscopic methods and X-ray crystallography. These compounds are building blocks for the syntheses of the surfactants containing polyperfluoromethylene spacer. The molecule has extended all-trans conformation with molecular symmetry (1) over bar (C-i). There is a reasonably strong C-H ... O interaction in the crystal and there are two F ... F intermolecular contact distances less than the sum of van der Waals radii. (C) 1999 Elsevier Science B.V. All rights reserved.

Item Type: Article
Subjects: D Physical Science > Physics
Divisions: Department of > Physics
Depositing User: Users 23 not found.
Date Deposited: 17 Jun 2021 07:26
Last Modified: 07 Dec 2022 05:21
URI: http://eprints.uni-mysore.ac.in/id/eprint/16806

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