Synthesis and characterization of binuclear metal phthalocyanine complexes

Achar, B. N. and Jayasree, P. K. (1999) Synthesis and characterization of binuclear metal phthalocyanine complexes. Indian Journal of Chemistry Section a-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry, 38 (6). pp. 558-562.

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Abstract

Hexasulphonated binuclear complexes of copper, nickel and cobalt phthalocyanines, M2PHS . 12H(2)O, where M=Cu, Ni or Co and PHS=Hexasulphonated phthalocyanine] are synthesized and characterized by elemental analysis, UV-Vis, Infrared, X-ray diffraction, magnetic susceptibility, ESR, TGA and electrical conductivity studies both before and after iodine doping. The remarkable increase in the electrical conductivities similar to 10(6)-10(7) times after iodine doping may be due to the arrangement of molecules in close facial proximity and the presence of partial oxidation states in the arranged molecular stackings.

Item Type:	Article
Subjects:	C Chemical Science > Chemistry
Divisions:	Department of > Chemistry
Depositing User:	Users 23 not found.
Date Deposited:	17 Jun 2021 06:37
Last Modified:	08 Jul 2022 06:11
URI:	http://eprints.uni-mysore.ac.in/id/eprint/16798

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