Synthesis, Crystal Structure and Characterization of (Z)-2-N′-hydroxyisonicotinamidine

Prabhuswamy, M. and Dinesha, and Pampa, K. J. and Madan Kumar, S. and Nagaraja, G. K. and Lokanath, N. K. (2014) Synthesis, Crystal Structure and Characterization of (Z)-2-N′-hydroxyisonicotinamidine. Molecular Crystals and Liquid Crystals, 593 (1). pp. 243-252.

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Official URL: http://dx.doi.org/10.1080/15421406.2013.875735

Abstract

The compound (Z)-2-N′-hydroxyisonicotinamidine, (2) was synthesized and characterized by 1H NMR, FT-IR, FAB-Mass, UV-Visible Spectra, and elemental Analysis. Its molecular structure was solved by single crystal X-ray diffraction method. The title molecule, C6H7N3O is crystallized in the orthorhombic crystal system with the space group Pna21 and with unit cell parameters a = 12.5664(8) Å, b = 8.8622(6) Å, c = 5.7953(4) Å, α = 90°, β = 90°, γ = 90°, and Z = 4. The molecular and crystal structure of the title molecule is stabilized by an intramolecular interaction of the type N—H···O, and the intermolecular interactions of types N—H···N and O—H···N.

Item Type: Article
Subjects: Physical Sciences > Physics
Divisions: PG Campuses > Manasagangotri, Mysore > Physics
Depositing User: Kodandarama
Date Deposited: 05 Jun 2014 06:06
Last Modified: 05 Jun 2014 06:06
URI: http://eprints.uni-mysore.ac.in/id/eprint/16788

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