Oxidation of para-Methoxy Benzaldehyde and salicylaldehyde by N-Sadio-N-Chlorotouene Sulphonamide (Chloramine-T) in acid Medium: A Kinetic and Mechanistic Study.

Revathi, S.K. and Rangaswamy and Ananda, S. (1999) Oxidation of para-Methoxy Benzaldehyde and salicylaldehyde by N-Sadio-N-Chlorotouene Sulphonamide (Chloramine-T) in acid Medium: A Kinetic and Mechanistic Study. Asian Journal of Chemistry, 11 (4). pp. 1271-1275.

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Abstract

The kinetics of the oxidation of para-methoxy benzaldehyde and salicylaldehyde by chloramine-B (CAB) have been studied in hydrochloric acid medium at 303 K. The rate shows first order dependence on CAB] and fractional order in aldehyde]. The rate increases with increase of HCl] and shows first order dependence on H+] and Cl-]. Variation of ionic strength, the addition of reaction product (benzene sulphonamide), and change in dielectric constant of the medium had no significant effect on the reaction rate. Thermodynamic parameters were evaluated.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: lpa venkatesh user
Date Deposited: 21 Jun 2021 06:17
Last Modified: 21 Jun 2021 06:17
URI: http://eprints.uni-mysore.ac.in/id/eprint/16767

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