Revathi, S. K. and Rangaswamy and Ananda, S. (1999) Oxidation of para-Methoxy Benzaldehyde and salicylaldehyde by N-Sadio-N-Chlorotouene Sulphonamide (Chloramine-T) in acid Medium: A Kinetic and Mechanistic Study. Asian Journal of Chemistry, 11 (4). pp. 1271-1275.
Full text not available from this repository. (Request a copy)Abstract
The kinetics of the oxidation of para-methoxy benzaldehyde and salicylaldehyde by chloramine-B (CAB) have been studied in hydrochloric acid medium at 303 K. The rate shows first order dependence on CAB] and fractional order in aldehyde]. The rate increases with increase of HCl] and shows first order dependence on H+] and Cl-]. Variation of ionic strength, the addition of reaction product (benzene sulphonamide), and change in dielectric constant of the medium had no significant effect on the reaction rate. Thermodynamic parameters were evaluated.
| Item Type: | Article |
|---|---|
| Subjects: | C Chemical Science > Chemistry |
| Divisions: | Department of > Chemistry |
| Depositing User: | Users 23 not found. |
| Date Deposited: | 21 Jun 2021 06:17 |
| Last Modified: | 03 Mar 2023 06:17 |
| URI: | http://eprints.uni-mysore.ac.in/id/eprint/16767 |
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