Oxidation of some primary amines by bromamine-b in alkaline medium: A kinetic and mechanistic study

Ananda, S. and Demappa, T. and Mahadevappa, D.S. and Gowda, N.M.M. (1996) Oxidation of some primary amines by bromamine-b in alkaline medium: A kinetic and mechanistic study. International Journal of Chemical Kinetics, 28 (12). pp. 873-878.

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Official URL: https://doi.org/10.1002/(SICI)1097-4601(1996)28:12...

Abstract

The kinetics of oxidation of the aliphatic primary amines, n-propylamine, n-butylamine, and isoamylamine, by sodium N-bromobenzenesulfonamide or bromamine-B (BAB) in sodium hydroxide medium has been studied at 35 degrees C. The reaction rate shows a first-order dependence each on BAB] and amine], and fractional order on OH-]. Additions of halide ions and the reduction product of BAB (benzenesulfonamide), and variation of ionic strength and dielectric constant of the medium do not have any significant effect on the reaction rate. Activation parameters have been evaluated. A Taft linear free-energy relationship is observed for the reaction with p*=-3.0 and delta=-2.0 indicating that electron-donating groups enhance the rate. An isokinetic relationship is observed with beta=393 K indicating that enthalpy factors control the rate. The existence of the relationship has been supported by the Exner criterion. Mechanisms consistent with the observed kinetic data have been proposed. (C) 1996 John Wiley & Sons, Inc.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: lpa venkatesh user
Date Deposited: 24 May 2021 06:59
Last Modified: 24 May 2021 06:59
URI: http://eprints.uni-mysore.ac.in/id/eprint/16540

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