Venkatesha, B. M. and Ananda, S. and Mahadevappa, D. S. (1991) Oxidation of aliphatic esters by sodium N-bromobenzenesulphonamide: A kinetic study. Indian Journal of Chemistry Section a-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry, 30 (9). pp. 789-792.
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Oxidation of aliphatic esters by sodium N-bromobenzenesulphonamide- A kinetic study.pdf Restricted to Registered users only Download (836kB) | Request a copy |
Abstract
Kinetics of oxidation of methyl, ethyl, propyl, isopropyl and n-butyl acetates by bromamine-B (BAB) have been studied in aqueous HCl medium at 40-degrees-C. The reaction rate shows first order dependence in oxidant] and fractional order each in H+] and ester]. Added halide ions and the reaction product benzenesulphonamide and variation of ionic strength and dielectric constant of medium do not have any significant effect on the rate. The oxidation of esters follows two mechanistic pathways namely an acid-independent and an acid-dependent path. A mechanism consistent with experimental results has been proposed.
| Item Type: | Article |
|---|---|
| Subjects: | C Chemical Science > Chemistry |
| Divisions: | Department of > Chemistry |
| Depositing User: | Users 23 not found. |
| Date Deposited: | 12 May 2021 04:52 |
| Last Modified: | 07 Jan 2023 06:01 |
| URI: | http://eprints.uni-mysore.ac.in/id/eprint/16361 |
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