Dobbler broadened and ionic conductivity studies on NASICON analogue

Ravindrachary, V. and Sreeramalu, V. and Sreepad, H. R. and Chandrashekara, A. and Gopal, S. (1991) Dobbler broadened and ionic conductivity studies on NASICON analogue. Solid State Ionics, 48 (1-2). pp. 173-176.

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Official URL: https://doi.org/10.1016/0167-2738(91)90212-T

Abstract

Doppler broadened lineshape and ionic conductivity measurements have been made in the NASICON analogue Na2(La, Al)Zr(PO4)3 synthesized with four different concentrations of ZrO2 (2, 2.2, 2.8 and 5.2 by wt.%) in the nutrient at room temperature. The lineshape parameter S is calculated for each concentration and it shows maximum value and the a.c. ionic conductivity sigma-shows minimum value for the material with 2.8 (wt.%) concentration of ZrO2 in the nutrient. An attempt has been made in correlating the changes in S parameter with sigma. The results show that the defect density is maximum for the material with 2.8 (wt.%) concentration of ZrO2 for which the conduction paths of Na+ ion are restricted.

Item Type: Article
Subjects: D Physical Science > Physics
Divisions: Department of > Physics
Depositing User: Users 23 not found.
Date Deposited: 11 May 2021 11:00
Last Modified: 28 Oct 2022 05:31
URI: http://eprints.uni-mysore.ac.in/id/eprint/16358

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