Crystal-Structure of Monochloro Trinitro Cu(Ii) Lignocaine Complex

Indira, A. and Babu, A. M. and Bellad, S. B. and Sridhar, M. A. and Shashidhara Prasad, J. and Prout, C. K. (1993) Crystal-Structure of Monochloro Trinitro Cu(Ii) Lignocaine Complex. Current Science, 64 (4). pp. 247-252.

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Abstract

The crystal structure of monochloro trinitro copper (II) lignocaine complex, CuC28H44O11N7Cl, has been determined by X-ray diffraction using CuK(alpha) radiation. The compound crystallizes in the monoclinic space group P 2(1)/n with unit cell parameters a=10.554(2) angstrom, b = 24.402(7)angstrom, c = 14.124(3) angstrom, beta = 100.025(20)-degrees with Z = 4, D(c) = 1398 Mg m-3, D(m) = 1.391 Mg m-3, mu = 2.08 mm-1. The structure was solved using 5242 reflections I > 2.5sigma (I)] out of 6764 reflections using MULTAN. The final residuals are R(f) = 0.120 (R(w) = 0.109). The copper coordination is seven in.the complex. The plane of one of the nitrate groups almost bisects the molecule.

Item Type:	Article
Subjects:	D Physical Science > Physics
Divisions:	Department of > Physics
Depositing User:	Users 23 not found.
Date Deposited:	04 May 2021 06:14
Last Modified:	07 Dec 2022 07:07
URI:	http://eprints.uni-mysore.ac.in/id/eprint/16328

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