Preparation and Structural Studies of Metal (Ii)-1,3,8,10,15,17,22,24-Octanitrophthalocyanines

Achar, B. N. and Bhandari, J. M. (1993) Preparation and Structural Studies of Metal (Ii)-1,3,8,10,15,17,22,24-Octanitrophthalocyanines. Transition Metal Chemistry, 18 (4). pp. 423-426.

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An efficient method for preparing pure 1,3,8,10,15,17,22,24-octanitrophthalocyanine derivatives of copper(II) (CuPON), cobalt(II) (CoPON) and nickel(II) (NiPON) has been developed. Elemental analysis, electronic spectra, i.r. spectra, magnetic susceptibility measurements, thermogravimetry and powder X-ray diffraction studies were done in order to check the purity, structural integrity, thermal stability and crystallinity of these complexes. Susceptibility measurements showed a variation in the magnetic moments of the complexes with magnetic field strength, indicating the presence of intermolecular cooperative effects.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: Users 23 not found.
Date Deposited: 07 May 2021 05:29
Last Modified: 08 Jul 2022 06:14

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