Swaroop, Toreshettahally R. and Wang, Zi-Qiang and Li, Qian-Yu and Wang, Heng Shan (2020) Reductive Coupling of Aromatic Aldehydes and Ketones Under Electrochemical Conditions. Journal of the Electrochemical Society, 167 (4). ISSN 1945-7111
Full text not available from this repository. (Request a copy)Abstract
Reductive coupling of o-substituted carbonyl compounds and m-substituted carbonyl compounds by the direct transfer of electron to carbonyl group respectively gave 1-(4-(1-hydroxy-1-phenylethyl/methyl)phenyl)ethanones/methanones and 2,3-bis(3-substitutedphenyl)butane/ethane-2,3-diols. 4-Methoxyacetophenone surprisingly gave 4-methoxybenzoic acid as oxidation product. Even acetophenone conjugated with alkyne group afforded interesting reductive addition product. Finally, imine also furnished reductively coupled diamino compound. Probable mechanisms for the formation of products is proposed. (c) 2020 The Electrochemical Society (''ECS''). Published on behalf of ECS by IOP Publishing Limited.
| Item Type: | Article |
|---|---|
| Subjects: | C Chemical Science > Organic Chemistry |
| Divisions: | Department of > Organic Chemistry |
| Depositing User: | Mr Umendra uom |
| Date Deposited: | 12 Feb 2021 05:36 |
| Last Modified: | 12 Feb 2021 05:36 |
| URI: | http://eprints.uni-mysore.ac.in/id/eprint/15636 |
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