Spectral evidence for generic charge -> acceptor interactions in carbamates and esters

Prabhakaran, Erode N. and Tumminakatti, Shama and Vats, Kamal and Ghosh, Sudip (2020) Spectral evidence for generic charge -> acceptor interactions in carbamates and esters. RSC Advances, 10 (20). pp. 11871-11875. ISSN 2046-2069

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Abstract

The correlations of the H-1 NMR, C-13 NMR and FT-IR spectral data from the R-O-C = O groups in the alkyl carbamates and esters of homologous alcohols reveal R-group-dependent negative charge stabilization at the carbonyl oxygen and their donation to generic acceptors at C-alpha of even alkyl alcohols (R), which explains several of their apparently anomalous properties.

Item Type: Article
Subjects: C Chemical Science > Organic Chemistry
Divisions: Department of > Organic Chemistry
Depositing User: Mr Umendra uom
Date Deposited: 23 Feb 2021 06:36
Last Modified: 23 Feb 2021 06:36
URI: http://eprints.uni-mysore.ac.in/id/eprint/15609

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