Shamanth, S. and Chaithra, N. and Gurukiran, M. and Mamatha, M. and Lokanath, N. K. and Rangappa, K. S. and Mantelingu, K. (2020) I-2-Catalyzed transformation of o-aminobenzamide to o-ureidobenzonitrile using isothiocyanates. Organic & Biomolecular Chemistry, 18 (14). pp. 2678-2684. ISSN 1477-0539
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Official URL: https://doi.org/10.1039/d0ob00118j
Abstract
The present work describes an unexpected and unique protocol for the iodine catalysed synthesis of o-ureidobenzonitriles using o-aminobenzamides and isothiocyanates via intramolecular rearrangement. The metal-free route achieved here is insensitive to moisture and applicable to the synthesis of a wide variety of o-ureidobenzonitriles with excellent yields even in a scalable fashion.
| Item Type: | Article |
|---|---|
| Subjects: | C Chemical Science > Chemistry |
| Divisions: | Department of > Chemistry |
| Depositing User: | Mr Umendra uom |
| Date Deposited: | 16 Feb 2021 06:30 |
| Last Modified: | 12 Sep 2022 09:50 |
| URI: | http://eprints.uni-mysore.ac.in/id/eprint/15598 |
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