Synthesis of novel Cubane Ni-4(O boolean AND O)(4) (OCH3)(4)(OOH)(4)] cluster: XRD/HSA-interactions, spectral, DNA-binding, docking and subsequent thermolysis to NiO nanocrystals

Hema, K. and Karthik, C. S. and Lokanath, N. K. and Mallu, P. and Zarrouk, Abdelkader and Salih, Kifah S. M. and Warad, Smail (2020) Synthesis of novel Cubane Ni-4(O boolean AND O)(4) (OCH3)(4)(OOH)(4)] cluster: XRD/HSA-interactions, spectral, DNA-binding, docking and subsequent thermolysis to NiO nanocrystals. Journal of Molecular Liquids, 315.

Text 1-s2.0-S0167732220331251-main (1).pdf - Published Version Restricted to Repository staff only Download (3MB) | Request a copy

Abstract

Under liquid-state vibration ultrasonic mode, the Ni-4(O boolean AND O)(4)(OCH3)(4)(OOH)(4) complex O boolean AND O-bidentate ligand = 4,4,4-trifluoro- 1 -phenylbutane-1.3-d ione] was synthesized from metal precursor and ligand in 10% H2O2/MeOH media, as a novel Ni-4(mu(3)-O)(4)]atbane duster. The XRD-structure of the desired duster was unraveled that each Ni (II) metal center possesses a distorted octahedral geometry. Monitored thermal treatment to the tetranudear metal cluster in an open atmosphere afforded nanocrystalline rod-shaped nickel oxide. Moreover, CHN-EA, FT-IR, conductivity measurement, UV-Vis., EDX, SEM, TG/DTA, and PXRD have confirmed the structure of the new cluster and NiO nanocrystals. The XRD-lattice interactions were explored to evaluate their role via computational Hirshfeld surface analysis. The molecular docking of the cluster with SS-DNA was estimated and demonstrated. (C) 2020 Published by Elsevier B.V.

Item Type:	Article
Uncontrolled Keywords:	Ni(II) cluster; NiO; Tetranuclear; Thermolysis; XRD; DFT
Subjects:	D Physical Science > Physics
Divisions:	Department of > Physics
Depositing User:	Mr Umendra uom
Date Deposited:	26 Mar 2021 10:50
Last Modified:	26 Mar 2021 10:50
URI:	http://eprints.uni-mysore.ac.in/id/eprint/15503

Actions (login required)

View Item