Development of a New Arylamination Reaction Catalyzed by Polymer Bound 1,3-(Bisbenzimidazolyl) Benzene Co(Ii) Complex and Generation of Bioactive Adamanate Amines

Chumadathil Pookunoth, Baburajeev and Eshwar Rao, Shilpa and Deveshegowda, Suresha Nayakanahundi and Kashinath Metri, Prashant and Fazl-Ur-Rahman, Kashifa and Periyasamy, Ganga and Virupaiah, Gayathri and Priya, Babu Shubha and Pandey, Vijay and E. Lobie, Peter and Knchugarakoppal Subbegowda, Rangappa and Basappa (2020) Development of a New Arylamination Reaction Catalyzed by Polymer Bound 1,3-(Bisbenzimidazolyl) Benzene Co(Ii) Complex and Generation of Bioactive Adamanate Amines. Catalysts, 10 (11). ISSN 2073-4344

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Abstract

We herein report the preparation and characterization of an inexpensive polymer supported 1,3-bis(benzimidazolyl)benzeneCo(II) complex PS-Co(BBZN)Cl-2] as a catalyst by using the polymer (divinylbenzene cross-linked chloromethylated polystyrene), on which 1,3-bis(benzimidazolyl)benzeneCo(II) complex (PS-Co(BBZN)Cl-2) has been immobilized. This catalyst was employed to develop arylamination reaction and robustness of the same reaction was demonstrated by synthesizing various bioactive adamantanyl-tethered-biphenylamines. Our synthetic methodology was much improved than reported methods due to the use of an inexpensive and recyclable catalyst.

Item Type: Article
Uncontrolled Keywords: arylamination reactions; adamantanyl-tethered-biphenylamines; polymer-supported catalyst; cobalt complex; Buchwald– Hartwig reaction
Subjects: C Chemical Science > Organic Chemistry
Divisions: Department of > Organic Chemistry
Depositing User: Mr Umendra uom
Date Deposited: 26 Mar 2021 10:02
Last Modified: 26 Mar 2021 10:02
URI: http://eprints.uni-mysore.ac.in/id/eprint/15482

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