Development of a New Arylamination Reaction Catalyzed by Polymer Bound 1,3-(Bisbenzimidazolyl) Benzene Co(Ii) Complex and Generation of Bioactive Adamanate Amines

Baburajeev, C. P. and Shilpa E. Rao and Deveshegowda, S. N. and Kashinath Metri, Prashant and Fazl-Ur-Rahman, K. and Ganga, P. and Gayathri Virupaiah and Priya B. S. and Pandey, Vijay and E. Lobie, Peter and Rangappa, K. S. and Basappa (2020) Development of a New Arylamination Reaction Catalyzed by Polymer Bound 1,3-(Bisbenzimidazolyl) Benzene Co(Ii) Complex and Generation of Bioactive Adamanate Amines. Catalysts, 10 (11). ISSN 2073-4344

Text Eprints.pdf - Published Version Restricted to Repository staff only Download (8MB) | Request a copy

Abstract

We herein report the preparation and characterization of an inexpensive polymer supported 1,3-bis(benzimidazolyl)benzeneCo(II) complex PS-Co(BBZN)Cl-2] as a catalyst by using the polymer (divinylbenzene cross-linked chloromethylated polystyrene), on which 1,3-bis(benzimidazolyl)benzeneCo(II) complex (PS-Co(BBZN)Cl-2) has been immobilized. This catalyst was employed to develop arylamination reaction and robustness of the same reaction was demonstrated by synthesizing various bioactive adamantanyl-tethered-biphenylamines. Our synthetic methodology was much improved than reported methods due to the use of an inexpensive and recyclable catalyst.

Item Type:	Article
Uncontrolled Keywords:	arylamination reactions; adamantanyl-tethered-biphenylamines; polymer-supported catalyst; cobalt complex; Buchwald– Hartwig reaction
Subjects:	C Chemical Science > Organic Chemistry
Divisions:	Department of > Organic Chemistry
Depositing User:	Mr Umendra uom
Date Deposited:	26 Mar 2021 10:02
Last Modified:	16 Jul 2022 07:03
URI:	http://eprints.uni-mysore.ac.in/id/eprint/15482

Actions (login required)

View Item