Made Gowda, N. M. and Mahadevappa, D. S. (1979) Kinetics of oxidation of glycine and valine by chloramine-T in hydrochloric acid medium. Monatshefte für Chemie, 110 (1). pp. 157-165. ISSN 0026-9247
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The kinetics of oxidation of glycine and valine by chloramine-T in hydrochloric acid medium has been studied. The rate of disappearance of chloramine-T shows a first order dependence on both chloramine-T and the amino acid, and an inverse first order with respect to [H+]. The solvent isotope effect was studied using heavy water. The kinetic parameters, Ea, Arrhenius factor A, ΔH≠ and ΔS≠ and ΔG≠ have been calculated. A rate law in agreement with experimental results has been derived. A mechanism is proposed.
| Item Type: | Article |
|---|---|
| Additional Information: | Publisher: Springer-Verlag |
| Subjects: | C Chemical Science > Chemistry |
| Divisions: | Department of > Chemistry |
| Depositing User: | Dhruva Kumar |
| Date Deposited: | 10 Jun 2021 06:10 |
| Last Modified: | 06 Jul 2022 07:52 |
| URI: | http://eprints.uni-mysore.ac.in/id/eprint/13919 |
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